![]() Exploring a naturally tailored small molecule for stretchable, self-healing, and adhesive supramolecular polymers. Transparent, highly stretchable, rehealable, sensing, and fully recyclable ionic conductors fabricated by one‐step polymerization based on a small biological molecule. Structural characteristics of synthetic amorphous calcium carbonate. Crosslinking ionic oligomers as conformable precursors to calcium carbonate. Hydrogels from amorphous calcium carbonate and polyacrylic acid: bio-inspired materials for “mineral plastics”. Organic–inorganic nanocomposites with completely defined interfacial interactions. Recent Developments in Polymer Macro, Micro and Nano Blends (Woodhead Publishing, 2017). In situ TEM imaging of CaCO 3 nucleation reveals coexistence of direct and indirect pathways. Principles of crystal nucleation and growth. Mechanisms of nucleation and growth of nanoparticles in solution. Recent progress in hybrid materials science. Über molekülbildung als frage des atombaus. Nanostructured organic–inorganic composite materials by twin polymerization of hybrid monomers. Applications of advanced hybrid organic–inorganic nanomaterials: from laboratory to market. Recent advances and remaining challenges for polymeric nanocomposites in healthcare applications. Printable organometallic perovskite enables large-area, low-dose X-ray imaging. Advanced hybrid nanomaterials for biomedical applications. Recent advances in organic and organic–inorganic hybrid materials for piezoelectric mechanical energy harvesting. Molecular dynamics of flexible polar cations in a variable confined space: toward exceptional two-step nonlinear optical switches. In situ nanoparticle embedding for authentication of epoxy composites. Fiber-based biopolymer processing as a route toward sustainability. Mesocrystalline calcium silicate hydrate: a bioinspired route toward elastic concrete materials. Polymer/silica nanocomposites: preparation, characterization, properties, and applications. Composites with carbon nanotubes and graphene: an outlook. The bottom-up creation of organic–inorganic hybrid molecules provides a feasible pathway for the molecular engineering of hybrid materials, thereby supplementing the classical methodology used for the manufacture of organic–inorganic hybrid materials. The coexistence of ceramic-like, rubber-like and plastic-like behaviours within poly(TA–CCO) goes beyond current classifications of materials to generate an ‘elastic ceramic plastic’. The reversible binding of Ca 2+–CO 3 2− bonds in the ionic network and S–S bonds in the covalent network ensures material reprocessability with plastic-like mouldability while preserving thermal stability. ![]() ![]() The two networks are interconnected through TA–CCO complexes to form a covalent–ionic bicontinuous structure within the resulting hybrid material, poly(TA–CCO), which unifies paradoxical mechanical properties. Its dual reactivity involving copolymerization of the organic TA segment and inorganic CCO segment generates the respective covalent and ionic networks. A combination of the organic covalent thioctic acid (TA) and the inorganic ionic calcium carbonate oligomer (CCO) through an acid–base reaction provides a TA–CCO hybrid molecule with the representative molecular formula TA 2Ca(CaCO 3) 2. Here we integrate typical covalent and ionic bonds within one molecule to create an organic–inorganic hybrid molecule, which can be used for bottom-up syntheses of hybrid materials. Although organic–inorganic hybrid materials have played indispensable roles as mechanical 1, 2, 3, 4, optical 5, 6, electronic 7, 8 and biomedical materials 9, 10, 11, isolated organic–inorganic hybrid molecules (at present limited to covalent compounds 12, 13) are seldom used to prepare hybrid materials, owing to the distinct behaviours of organic covalent bonds 14 and inorganic ionic bonds 15 in molecular construction. ![]()
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